Product ID:ASPHALT ROLLED ROOFING PRODUCTS, GLASBASE
MSDS Date:01/01/1993
FSC:5640
NIIN:00N055645
MSDS Number: BWBNL

MANVILLE SALES CORP

717 17TH ST
DENVER, CO 80217-5108
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 303-978-4900

Cage: 75165

SCHULLER INTERNATIONAL INC.

5108 DENVER, CO 80217-5108 US

Telephone: 303-978-4900

Cage: 75165

ASPHALT (PETROLEUM); (PETROLEUM ASPHALT)

CAS: 8052-42-4

RTECS: CI9900000

Fraction By Weight: 20-75%

OSHA PEL N/K

ACGIH TLV: 5 MG/M3; FUME

MINERALS; (MINERAL GRANULES)

Fraction By Weight: 40-45%

OSHA PEL N/K

ACGIH TLV: N/K

DOLOMITE; (INERT MINERAL FILLER (DOLOMITE))

CAS: 16389-88-1

Fraction By Weight: 15-40%

OSHA PEL 5 MG/M3 RDUST (MFR)

ACGIH TLV: 10 MG/M3 TDUST (MFR)

FIBERGLASS (FIBROUS GLASS); (FIBROUS GLASS MAT

CAS: 65997-17-3

Fraction By Weight: 1-25%

OSHA PEL 5 MG/M3 RESP DUST

ACGIH TLV: 10 MG/M3 (<7MICRONS)

SCRATCHED. FLUSH EYES W/LG AMTS OF WATER

RTECS: 9999999ZZ

PROD IS MECH IRRIT & IS NOT EXPECTED TO

RTECS: 9999999ZZ

TREATMENT SHOULD BE DIRECTED TOWARD REMOVING SOURCE

RTECS: 9999999ZZ

HYGIENIST, WHILE DESIGN OF SPECIFIC VENTILATION

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MATL IS MECH IRRIT TO SKIN, EYES
& UPPER RESP SYS. INHAL: IRRIT OF UPPER RESP TRACT (SCRATCHY
THROAT), COUGH & CONGESTION MAY OCCUR IN EXTREME OVEREXP.
SKIN/EYES: TEMPORARY IRRIT (ITCHING) OR RE DNESS MAY OCCUR. INGEST:
IRRIT OF GI TRACT MAY OCCUR. CHRONIC: INHAL OF DUST/FIBERS FROM
PROD IS NOT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FIBROUS GLASS: IARC GRP 2B,V 8,P
289,1973: CRYSTALLINE SILICA: IARC GRP 2A, SUP 7,P 341,1987; ANTIC
CARCIN, NTP 7TH RPT.
Effects of Overexposure:HLTH HAZ: LIKELY TO OCCUR DUE TO INTENDED USE &
PROD FORM. CRYSTALLINE SILICA CAN CAUSE SILICOSIS, NONCANCEROUS
LUNG DISEASE CAUSED BY EXCESS EXPOS TO CRYSTALLINE SILICA. NO
CHRONIC HLTH EFTS KNOWN TO BE ASSOC W/EXPOS TO CONTINUOUS FILAMENT
FIBER GLASS. TARGET ORGANS: UPPER RESP SYS, SKIN & EYES.
Medical Cond Aggravated by Exposure:AS WITH ANY DUST, PRE-EXISTING
UPPER RESPIRATORY AND LUNG DISEASES MAY BE AGGRAVATED.

First Aid:INHAL: REMOVE TO FRESH AIR. DRINK WATER TO CLEAR THROAT &
BLOW NOSE TO REMOVE DUST. SKIN: WASH GENTLY W/SOAP & WARM WATER TO
REMOVE DUST & FIBERS. INGEST: PROD NOT INTENDED TO BE
INGESTED/EATEN. IF IN GESTED, TREAT SYMPTOMATICALLY. RINSE MOUTH
W/WATER TO REMOVE FIBERS & DRINK PLENTY OF WATER TO HELP REDUCE
IRRIT. EYES: DO NOT RUB/SCRATCH EYES. DUST PARTICLES MAY CAUSE LENS
OF EYE TO BE (ING 5)

Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL ABC RATED.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
BURNING WILL PRDCE THICK BLACK SMOKE; HOWEVER, NO SPECIAL
PROCEDURES ARE EXPECTED TO BE NEC FOR THIS PROD.
Unusual Fire/Explosion Hazard:NORMAL FIRE FIGHTING PROCEDURES SHOULD BE
FOLLOWED TO AVOID INHALATION OF SMOKE AND GASES.

Spill Release Procedures:PICK UP LARGE PIECES, VACUUM DUSTS. IF
SWEEPING IS NECESSARY, USE DUST SUPPRESSANT (SUCH AS WATER). DO NOT
DRY SWEEP DUSTS. THESE PROCEDURES WILL HELP TO MINIMIZE POTENTIAL
EXPOSURES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MATERIAL SHOULD BE KEPT DRY &
PROTECTED FROM THE ELEMENTS. WAREHOUSE STORAGE SHOULD BE IN
ACCORDANCE WITH PACKAGE DIRECTIONS, IF ANY.
Other Precautions:USE PROTECTIVE EQUIPMENT WHEN HANDLING LOOSE OR
UNPACKAGED MATERIAL. PROTECTIVE EQUIPMENT SHOULD BE PROVIDED AS
NECESSARY TO PREVENT IRRITATION OF THE THROAT, EYES & SKIN & TO
KEEP EXPOSURES BELOW THE APPLICABLE EXPOSURE GUIDELINES.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROP FOR
EXPOSURE OF CONCERN . DUE TO INTENDED USE & PROD FORM NO
RESPIRATORY PROTECTION IS REQD. WHEN PROD IS USED W/ASPHALT OR COAL
TAR MASTICS, FOLLOW SPE CIFIC CAUTIONS FOR MATERIAL BEING USED.
Ventilation:NONE EXPECTED FOR NORM CNDTNS OF USE. THE NEED FOR VENT SYS
SHOULD BE EVALUATED BY PROFESSIONAL INDUSTRIAL (ING 8)
Protective Gloves:LEATHER OR COTTON GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:NONE.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING THE RESTROOM.
Supplemental Safety and Health
HAZ DECOMP PROD: BURNING OF POLYMER. THESE DECOMP PRODS MAY INCL CARBON
DIOXIDE, CARBON MONOXIDE, CARBON PARTICLES & HYDROCARBONS.

HCC:N1
Boiling Pt:B.P. Text:>698F,>370C
Melt/Freeze Pt:M.P/F.P Text:>203F,>95C
Spec Gravity:1.2-1.6(H*2O=1)
Solubility in Water:0
Appearance and Odor:DARK MAT WITH TALC OR SAND SURFACE; ASPHALT ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
MATERIAL IS INCOMPATIBLE WITH STRONG OXIDIZERS, REDUCING AGENTS, STRONG
ACIDS AND ALKALIES.
Stability Condition to Avoid:DIRECT EXPOSURE TO VERY HIGH HEAT OR FLAME
SHOULD BE AVOIDED.
Hazardous Decomposition Products:THOSE THAT WOULD BE EXPECTED FROM ANY
ORGANIC (CARBON CONTAINING) MATL & ARE MAINLY DERIVED FROM
PYROLYSIS OR (SUPDAT)

Waste Disposal Methods:WASTES ARE NOT HAZARDOUS AS DEFINED BY RCRA (40
CFR 261). COMPLY WITH FEDERAL, STATE & LOCAL REGS FOR DISPOSAL OF
ASPHALT ROOFING PRODUCTS. IF UNSURE OF REGS, CONTACT LOCAL PUBLIC
HEALTH DEPARTMENT OR LOCAL OFFICE OF THE EPA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.